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MATERIAL SAFETY DATA SHEET
Date Prepared: 03/24/2000
MSDS No: 032
Spec+PlusThermo-Sealant
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1. Chemical Product and Company Identification
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Product Identifier: Spec+Plus Thermo-Sealant
Manufacturer
| Neyra Industries, Inc. 10700 Evendale Drive Cincinnati, OH 45241 |
Emergency Telephone Numbers CHEMTREC (800) 424-9300 24 hours Emergency Contact Customer Service Emergency Phone: 1-800-543-7077 |
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2. Composition/Information on Ingredients
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| COMPONENT | CAS# | % BY WT | TLV |
| Asphalt Cement | 8052-42-4 | < 55 | 5 mg/m3* |
| Petroleum Process Oil | 64742-04-7 | < 15 | N/D** |
| Crumb Rubber | < 20 | N/D** | |
| Calcium Carbonate | 1317-65-3 | < 25 | 10 mg/m3 total dust |
* Asphalt (petroleum) Fumes
** N/D = Not Determined
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3. Hazards Identification
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Emergency Overview
Immediate concerns: All persons working with hot bitumen should be familiar
with the following procedures in order to administer first aid to burn
victims. This document should accompany the patient and be placed in a
prominent position before transport to doctor or hospital. The key
recommendation is to involve the aid of a physician immediately.
NO ATTEMPT SHOULD BE MADE TO REMOVE THE BITUMEN IN THE FIELD.
This material has not been in long tested in long chronic exposure tests.
Potential Health Effects
Eyes: Contact with product at elevated temperatures can result in thermal
burns.
Skin: Contact with product at elevated temperatures can result in thermal
burns.
Ingestion: May cause vomiting. When asphaltic products are heated, they
often give off small amounts of hydrogen sulfide, which is an extremely
flammable, highly toxic gas.
Inhalation: When asphaltic products are heated, they often give off small
amounts of hydrogen sulfide, which is an extremely flammable, highly toxic
gas. Inhalation of vapors at elevated temperatures may cause irritation to
the nose, throat, and respiratory tract. Move to fresh air.
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4. First Aid Measures
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Eyes: If hot bitumen has entered the eye it should be flushed with water
until the bitumen has cooled. No attempt should be made to remove the bitumen
by unqualified personnel. The patient should be referred urgently for
specialist medical assessment and treatment.
Skin: When an accident occurred the affected area should be cooled as quickly
as possible to prevent the heat causing further damage. Bitumen has a high
specific heat capacity and is also a good insulator. For these reasons the
burn should be drenched in cold water for at least five minutes. However,
body hypothermia must be avoided. No attempt should be made to remove the
bitumen from the burned area.
FURTHER TREATMENT, FIRST AID AND MEDICAL CARE
The bitumen layer will be firmly attached to the skin and removal should NOT
be attempted unless carried out at a medical facility under the supervision
of a burns specialist. The cold bitumen will form a waterproof, sterile layer
over the burn which will prevent the burn from drying out. If the bitumen is
removed from the wound there is the possibility of complications.
Furthermore, by exposing a second degree burn in order to treat it there is
the possibility that infection or drying out will make the wound deeper.
SECOND DEGREE BURNS
The bitumen should be left in place and covered with a Tulle dressing
containing paraffin or a burn ointment containing paraffin, e. g. Flamzine (
silver sulphadiazine ). Such treatment will have the effect of softening the
bitumen enabling it to be gently removed over a period of days. As a result
of the natural re-epithelialsation of the wound any remaining bitumen will
peel off in time.
THIRD DEGREE BURNS
Active removal of the bitumen should be avoided unless primary surgical
treatment is being considered due to the location and depth of the wound. In
such cases removal of the bitumen is best carried out in the operating
theatre between the seconds and fifth day after the burn occurred. By the
second day the capillary circulation has usually removed and the bed of the
wound is such that a specialist can assess the depth to which the burn has
penetrated. There are normally no secondary problems such as infections to
contend with before the sixth day. However, it is essential to commence
treatment using paraffin based substances from the day of the accident to
facilitate removal during surgery.
CIRCUMFERENTIAL BURNS
Where hot bitumen completely encircles a limb or other body part the burned
tissue might swell under the cooled and hardened bitumen causing a tourniquet
effect. In the event of this occurring the bitumen should be softened as
described above.
Ingestion: Get medical attention immediately.
Inhalation: If exposed to excessive levels of dusts or fumes, remove to fresh
air and get medical attention if cough or other symptoms develop.
Antidotes: If swallowed, do NOT induce vomiting. Give victim a glass of water
or milk. Call a physician or poison control center immediately. Never give
anything by mouth to an unconscious person.
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5. Fire Fighting Measures
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Comments: Not Established
Flashpoint and Method: 585 degrees F
Comments: Not Established
Autoignition Temperature: None
Comments: None
Hazardous Combustion Products: Not Established
Other Considerations: "Empty" containers retain product residue (liquid
and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE
INJURY OR DEATH. Empty drums should be completely drained, properly bunged
and promptly returned to a drum reconditioner, or properly disposed of.
General Hazard: None
Fire Fighting Equipment: As in any fire, wear self-contained breathing
apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full
protective gear.
Flammable Class: None
Flame Propagation or Burning Rate of Solids: Not yet Determined
Fire Explosion: None
Fire Fighting Procedures: Do not use water on an asphalt fire since it may
cause a violent eruption and spread the burning asphalt.
Explosion Hazards: None
Extinguishing Media: Use dry chemical or CO2.
Sensitive Static Discharge: Not Established
Sensitivity to Impact: None
Comments: Not Established
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6. Accidental Release Measures
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Small Spill: The asphalt portion is classified as an oil. Spills entering
surface waters that cause a sheen must be reported to the national response
center at 1.800.424.8802. Contain material and allow to cool. Product is a
solid at room temperature. Avoid runoff into storm sewers and ditches which
lead to waterways. Absorb spill with suitable material. In soil, recover
the spilled material, put in closed containers for disposal. Dispose in a
safe manner in accordance with local, state and federal regulations. On
water, stop the leak and prevent it from spreading. Notify the proper
authorities. Avoid runoff into storm sewers and ditches which lead to
waterways. Do not flush to sewer.
Large Spill: For large spills, dike the area, allow the material to cool down
and place into closed containers. Prevent this material from entering
waterways.
Special Protective Equipment: Wear protective clothing during cleanup.
General Procedures: Keep spectators away from spill. Surface may be slippery,
use care to avoid falling.
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7. Handling and Storage
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Handling: Wash thoroughly after handling.
Storage: Keep away from heat, sparks and flame.
Loading Temperature: Not Established
Storage Temperature: 0 degrees F to 200 degrees F
Loading/Unloading Viscosity: Not Determined
Storage Pressure: Not Determined
General Procedures: Follow all MSDS/label precautions even after container is
emptied because they may retain product residues.
Electrostatic Accumulation Hazard: None
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8. Exposure Controls/Personal Protection
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Eyes and Face: Wear safety glasses with side shields (or goggles) and a face
shield.
Protective Clothing: This product can cause severe burns. All equipment used
in it is application should be well maintained with special emphasis given to
all safety features. Only heat outdoors. Long sleeve shirts and pants are
recommended while using this product.
Skin: When material is heated, wear gloves to protect against thermal burns.
Respiratory: Use a NIOSH approved respirator.
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9. Physical and Chemical Properties
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Physical State: Solid
Appearance: Shiny with granular appearance.
Color: Black.
Vapor Pressure: None
Melting Point: 180 degrees F
Boiling Point: >900 degrees F
pH: 7.0 to 10.0
Evaporation Rate: None
Density: 9.50 at 77 degrees F
Odor: Asphalt odor
Percent Volatile: 0
Specific Gravity: 1.16
Viscosity: Not Available
Vapor Density: Heavier
Water Solubility: None
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10. Stability and Reactivity
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Stable: Yes
Hazardous Polymer: No
Stability: Stable.
Polymerization: None.
Conditions to Avoid:
Incompatible Materials: Do not allow heated material to contact aqueous
materials or highly flammable materials as this can cause violent eruptions
due to steam generation or fires.
Hazardous Decomposition: A complex mixture of airborne solids, liquids and
gases will evolve when this material undergoes combustion. Stable.
However, may decompose if heated. When the dried material burns, steam,
carbon dioxide, carbon monoxide, and other toxic fumes may be emitted.
Notes: Do not heat above safe heating temperature. Hot asphalt may ignite
flammable mixtures.
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11. Toxicological Information
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12. Ecological Information
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Environmental Data: None
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13. Disposal Considerations
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Disposal Method: Dispose of the dried material in a safe manner in accordance
with federal, state and local regulations. Do not dispose of by means of
sinks, drains or in the immediate environment. Empty drums should be
completely drained, properly bunged, and returned to a drum reconditioner.
Drill a hole in the bottom of empty pails to prevent drowning of small
children.
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14. Transport Information
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15. Regulatory Information
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SARA Title III (Superfund Amendments and Reauthorization Act)
313 Reportable Ingredients: None
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16. Other Information
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Approval date: 05/25/2000
Approved by: Greg Houser Title: V. P. Manufacturing
Reason for Issue: New Format
Revision Summary: New MSDS
Information Contact: 1.800.543.7077
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| HMIS CODES: | 2 |
2 |
0 |
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NFPA CODES: | 2 |
2 |
0 |
- |
(Health, Fire, Reactivity, Protection)
This information is provided in good faith and correct to the best of Neyra Industries, Inc. knowledge as of the date here of; however, Neyra Industries,
Inc. makes no representation as to its completeness or accuracy. Customers are encouraged to make their own determination as to the suitability of this
product for their purpose prior to use. Neyra Industries, Inc. disclaims responsibility to damages of any kind resulting from the use of this
information.
THERE ARE NO WARRANTIES OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT IT DESCRIBES.